By William B. Tolman
The 1st to mix either the bioinorganic and the organometallic view, this guide offers all of the helpful wisdom in a single handy quantity. along a glance at CO2 and N2 aid, the authors speak about O2, NO and N2O binding and aid, activation of H2 and the oxidation catalysis of O2.
Edited by way of the hugely well known William Tolman, who has received a number of awards for his study within the box.
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Extra resources for Activation of Small Molecules: Organometallic and Bioinorganic Perspectives
Inomata, Y. Kawanami, Catal Lett 2002, 82, 193–197. (a) M. Aresta, E. Quaranta, Ital Pat 1198206, 1988; (b) M. Aresta, E. Quaranta, Tetrahedron 1991, 47, 9489–9502; (c) M. Aresta, E. Quaranta, Ital Pat 1237207, 1993; (d) M. Aresta, C. Berloco, E. Quaranta, Tetrahedron 1995, 51, 8073–8078; (e) M. Aresta, A. Bosetti, E. Quaranta, Ital Pat 002202, 1996; (f) M. Aresta, A. Dibenedetto, E. Quaranta, Tetrahedron 1998, 54, 14145–14156; (g) M. Aresta, A. Dibenedetto, E. Quaranta, Green Chem 1999, 1, 237–242; (h) M.
Such a performance is several times that of conventional catalysts for syngas conversion. 4 CO2 Conversion the methanol production from H2/CO2 is technically competitive with the industrial production from syngas, albeit economically still less convenient. The synthesis of methanol from CO2 and water can be carried out by using a cascade of enzymes that allow the conversion of CO2 into HCOO– (formate dehydrogenase), CH2O (formaldehyde dehydrogenase) and CH3OH (methanol dehydrogenases) [122, 123].
Thauera aromatica bacteria can use phenol as the only source of carbon under anaerobic conditions; phenol is eventually converted into CO2 and water. 4). The carboxylation of phenol is carried out by a phenolcarboxylase enzyme, a new type of lyase . The isolation of the enzyme from the cytoplasmic portion of the cell allows its use in vitro. In order to extend the lifetime of the enzyme, its supported form on low melting agar can be used . 4 Carboxylation of phenolphosphate to 4-hydroxybenzoic acid.