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2b-5) i n tetrahydrofuran would also probably i n i t i a t e t h i s polymer­ i z a t i o n but the product polymers would not be stereoregular and t h i s would therefore not be a p r a c t i c a l process. 43 9-2. (Cont'd) (c) A Levis acid or Levis acid s a l t i s a s u i t a b l e i n i t i a t o r tetrahydrofuran. See reactions for (9-60) and ( 9 - 6 1 ) , for example. Polymerization can be c a r r i e d out i n the b u l k , l i q u i d monomer or i n an i n e r t d i l u e n t l i k e methylene c h l o r i d e .

608 F3 - 1 - F2 - ΐ 8-3. 154. Use r e a c t i v i t y r a t i o from problem 8-2 [Mj] n i - — 12 When - [ϊςι r i + 1 · mole f r a c t i o n of eqs. 7 - [ M 2] [Mj] + [ M 2] 35 8-3. 7 " [ M 2] 1^ - average sequence length of m e t h a c r y l o n i t r i l e $2 9 average sequence length of styrene • 0 . 4 4 ( 0 . 43 21 eqs. 86. 8-4. 39 negative e, high Q: i . e . 60 positive e: i . e . 74 l i k e a c r y l o n i t r i l e has p o s i t i v e e and i s an e l e c t r o n acceptor. Butadiene Use r^rj r^rj as a measure of a l t e r n a t i o n .

01 ( 1 . 0 1 ) ( 1 1 , 8 0 0 ) - 11,900. 46 Chapter 10 10-1. 34 ( 1 . 4 0 ) (300) - 422. 42 0 . 6 6 K 2( 2 8 0 ) . The volume of che head space i n the p o l y m e r i z a t i o n reactor above the polymer melt i s independent of temperature. The vapor pressure (1 atm steam) also does noc vary w i t h temperature. L e t [H_0 ] ~ - concentration of water ·& # vap ZDU the head space at 250 C. in 47 10-1. ρ1 280 " 73 + 2 50 " assuming that the H^O vapor behaves as an i d e a l gas. 06 Η,Οv 1(250) J U J ;U C K.

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